Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine.
نویسندگان
چکیده
The dimetallic [M(2)(bpy)(2)(NO(3))(2)](NO(3))(2) moieties (M = Pd(II) or Pt(II)) react preferentially at the pyrazolyl end of the pyridyl-pyrazole ligand, giving rise to dimetallic corners. Subsequently, the dimetallic corner building blocks featuring two pyridine donors are coordinated by monometallic [M(bpy)(NO(3))(2)] moieties (M = Pd(II) or Pt(II)) to form homo- or hetero-metallomacrocycles.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 43 شماره
صفحات -
تاریخ انتشار 2012